Synonyms: Ethyl acetic ester, Ethyl ester, Ethyl ethanoate, Acetoxyethane. Other Languages: De: Ethylacetat. Es: Acetato de etilo. Ethyl acetate for liquid chromatography LiChrosolv®. CAS , EC Number , chemical formula CH₃COOC₂H₅. – Find MSDS or SDS, a COA. Details of the supplier of the safety data sheet Wordt ervan verdacht de vruchtbaarheid te schaden. STOT RE acetato de etilo.
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Excessive amounts of ethyl acetate are considered a wine fault. From Wikipedia, the free encyclopedia. Overexposure to ethyl acetate may cause irritation of the eyes, nose, and throat. Byproducts of the dehydrogenation include diethyl etherwhich is thought to arise primarily due to aluminum sites in the catalyst, acetaldehyde and its aldol products, higher esters, and ketones.
The use of an acid catalyst accelerates the hydrolysis, which is subject to the Fischer equilibrium mentioned above. Patty’s Industrial Hygiene and Toxicology.
Acetate esters Ethyl esters Flavors Ester solvents Commodity chemicals. Refractive index n D. The combined annual production in of Japan, North America, and Europe was abouttonnes. Ethyl acetate can be hydrolyzed in acidic or basic conditions to regain acetic acid and ethanol.
For example, it is commonly used to clean circuit boards and in some nail varnish removers acetone and acetonitrile are also used. In perfumes, it evaporates quickly, leaving only the scent of the perfume ,sds the skin. Ethyl acetate is rarely dw as a reaction solvent because it is prone to hydrolysis and transesterification.
These azeotropes are broken by pressure swing distillation or membrane distillation. Coffee beans and tea leaves are decaffeinated with this solvent. Catalytic technology for the sustainable society”.
Severe overexposure may cause weakness, drowsiness, and unconsciousness. Retrieved from ” https: In the field of entomologyethyl acetate is an effective asphyxiant for use in insect collecting and study. The Oxford Companion to Wine 3rd ed. Acetic ester Acetic ether Ethyl ester of acetic acid.
LD 50 median dose. Methyl acetatePropyl acetateButyl acetate. Exposure to oxygen can exacerbate the fault due to mmsds oxidation of ethanol to acetaldehydewhich leaves the wine with a sharp vinegar -like taste. Other names Acetic ester Acetic ether Ethyl ester of acetic acid. This page was last edited on 29 Novemberat Ethyl acetate is used primarily as a solvent and diluentbeing favored because of its low cost, low toxicity, and agreeable odor.
The irritant effect of ethyl acetate is weaker than that of propyl acetate or butyl acetate. Separations of the byproducts are complicated by the fact that ethanol forms an azeotrope with water, as does caetato acetate with ethanol and water, and methyl ethyl ketone MEK, which forms from 2-butanol with both ethanol and ethyl acetate. Surface area can be etiilo increased by deposition onto a zeolitetypically ZSM Given that the chemical is naturally present in many organisms, there is little risk of toxicity.
Ethyl acetate is the most common ester in winebeing the product of the most common volatile organic acid — acetic rtiloand the ethyl alcohol generated during the fermentation. The copper may have its surface area increased by depositing it on zincpromoting the growth of snowflake -like fractal structures dendrites. International Labour Office,p. Ethyl acetate is synthesized in industry etil via the classic Fischer esterification reaction of ethanol and acetic acid.
Views Read Edit View history. S16S26S Traces of rare-earth and alkali metals are beneficial to the process.
The reaction can be accelerated by acid catalysis and the equilibrium can be shifted to the right by removal of water. Silicotungstic acid is used to manufacture ethyl acetate by the alkylation of acetic acid by ethylene: It is also prepared in industry using the Tishchenko reactionby combining two equivalents of acetaldehyde in the presence of an alkoxide catalyst:.
The aroma of ethyl acetate is most vivid in younger wines and contributes towards the general perception of “fruitiness” in the wine.
A specialized industrial route entails the catalytic dehydrogenation of ethanol. Ether -like, msdd . In a killing jar charged with ethyl acetate, the vapors will kill the collected insect quickly without destroying it.
In rare cases exposure may cause sensitization of the mucous membrane and eruptions of the skin.